Synthesis of Nanostructured polyaniline, metal oxides for electrochemical biosensors, and energy conversion applications

PI Details Co-PI Details
Dr. Anu Prathap

Designation: Assistant Professor
Department: Metallurgical and Materials Engineering
Email ID: anuprathap@pec.edu.in

Funding Agency Project Cost
Department of Biotechnology India

 

Amount Received till date (in Rs.) 8696508

Start Date Completion Date Status
2019-04-01 2024-03-31 Ongoing
Abstract

The demand for materials based on nanotechnology has been identified as an essential component in a variety of applications. Among other applications, nano-based sensing devices have received considerable attention, especially in medical and environmental monitoring. Recent developments have enabled the fabrication and application of sensing devices. My research talk will consist of the basic concepts of the fabrication of different modified electrode based sensor. Similarly, the fabrication of bacteria sensor associated with urinary tract infections, herbicide atrazine, and electrochemical determination of cancer biomarker sensors will also be presented, highlighting its advantages over other conventional sensors, as reported by my recent publication. Flexible consumer electronic products, such as folding displays, health monitoring devices, smart fabrics, and flexible body sensors, have gotten a lot of attention since they can be utilised for flexible and wearable electronic gadgets. Lightweight, flexible, and large storage capacity are all requirements for an energy storage system to power these functional devices. Flexible supercapacitors, with their high power densities, extended life, and quick charge/discharge rates, have been highlighted as a possible solution for such needs. I am currently working on the development of high energy density conducting polymer based supercapacitor for energy storage applications. Energy conversion (EC) devices that are environmentally friendly and efficient are critical for the production of sustainable energy. Direct methanol fuel cells (DMFCs) are potential EC devices for supplying power to portable electronic devices and electric vehicles, with the slow methanol electrooxidation reaction (MEOR) kinetics at the anode being the main constraint. Platinum (Pt) is typically the most advantageous choice for electrocatalysis in the MEOR due to its distinct d-band configuration, which allows for rapid methanol adsorption and dissociation. However, the high cost and proclivity to poison render widespread commercial Platinum (Pt)-based electrocatalysis in DMFCs unviable. My attempt is to rationally integrate Copper, Nickel and Cobalt based materials in order to create a novel composite that could be used effectively in DMFCs. Hydrogen has been recognised as a future fuel that could help solve the energy crisis caused by fossil-fuel exhaustion. The most abundant element in the universe is hydrogen. Hydrogen has a higher combustion enthalpy and produces zero-pollution. Hydrogen (H2) fuel cells have a lot of potential in transportation and stationary applications, but their widespread commercialization is hampered by their expensive cost. Because platinum (Pt) is one of the most expensive components of a fuel cell, numerous R&D efforts have focused on ways to improve the activity, as well as platinum free catalysts for long-term applications. My research project also focuses on two ways to addressing catalyst challenges: low-Pt catalysts and Pt-free catalysts.

Manpower Sanctioned/Hired Manpower Trained

M.Tech. Produced: 1

 

Equipment Sanctioned/Procured

Name of Equipment

Make & Model

Year of Purchase

Cost

Salient Features of Equipment

Condition (Working /Not Working)

Potentiostat-Galvanostat

US, 1010 E

2021

Rs,6,53,000/-

Instrument is used for all electrochemical applications studies.

 

Working

 

Publications
List of SCI Publications under Project

Authors Name

Title of Paper

Journal Name

Volume No.

Page No.

Year

DOI Number

M. U. Anu Prathap, O Sadak, S. Gunasekaran

Metal–Organic Framework/Polyaniline Nanocomposites for Lightweight Energy Storage

ACS Applied Energy Materials

3

12368–12377

2020

https://doi.org/10.1021/acsaem.0c0237

 

M. U. Anu Prathap, B. Thakur, S.N. Sawant, R. Srivastava

Facile one-pot synthesis of CuO nanosheet for application as electrocatalyst for methanol oxidation

Journal of Physics and Chemistry of Solids

150

109883

2021

https://doi.org/10.1016/j.jpcs.2020.109883

 

H. Urena-Saborio, M. U. Anu Prathap, E. Alfaro-Viquez, S. Madrigal-Carballo, J. D. Reed, S.Gunasekaran

Cranberry Proanthocyanidins-PANI Nanocomposite for the Detection of Bacteria Associated with Urinary Tract Infections

Biosensors

 

11

2021

199

https://doi.org/10.3390/bios11060199

M. U. Anu Prathap

Electrochemical Detection of Herbicide Atrazine Using Porous MnO2-NiO Nanocatalyst

Materials Science and Engineering: B

290

2023

116302

https://doi.org/10.1016/j.mseb.2023.1

 


Output/Outcome of the Project
Output/Outcome of the project
  1. M. U. Anu Prathap, O Sadak, S. Gunasekaran, Metal–Organic Framework/Polyaniline Nanocomposites for Lightweight Energy Storage, ACS Applied Energy Materials 3 (2020) 12368–12377. Impact Factor: 6.959
    https://doi.org/10.1021/acsaem.0c02376
  2. M. U. Anu Prathap, B. Thakur, S.N. Sawant, R. Srivastava, Facile one-pot synthesis of CuO nanosheet for application as electrocatalyst for methanol oxidation, Journal of Physics and Chemistry of Solids 150 (2021) 109883. Impact Factor: 4.383
    https://doi.org/10.1016/j.jpcs.2020.109883 Impact Factor: 3.995
  3. MH. Urena-Saborio, M. U. Anu Prathap, E. Alfaro-Viquez, S. Madrigal-Carballo, J. D. Reed, S.Gunasekaran ( a =Shares equal contribution), Cranberry Proanthocyanidins-PANI Nanocomposite for the Detection of Bacteria Associated with Urinary Tract Infections, Biosensors 11 (2021) 199. Impact Factor: 5.743
    https://doi.org/10.3390/bios11060199
  4. Prathap M. Udayan, A. Electrochemical Detection of Herbicide Atrazine Using Porous MnO2-NiO Nanocatalyst. Materials Science and Engineering: B 2023, 290, 116302. Impact Factor: 3.407
    https://doi.org/10.1016/j.mseb.2023.116302
    Book Chapter
  5. M. U. Anu Prathap, Shilpa N Sawant, Synthesis of Advanced Nanomaterials for Electrochemical Sensor and Biosensor Platforms, Handbook on Synthesis Strategies for Advanced Materials, 2021, 27-69, Springer, Singapore.